O2 + CO -> O + CO2

SOURCE:

Warnatz, J. (1984) in Combustion Chemistry, W.C. Gardiner, Ed., Springer-Verlag, Chap. 5.

COMMENTS:

This expression originates from early shock-tube measurements of CO-enhancement of ignition of H2-O2 mixtures and has not been revisited with modern shock tube methods.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        -6.7        -8.1    3.77E-23    1.42E-27    2.66E+04
     500        -6.3        -7.9    3.20E-09    2.64E-11    1.21E+02
    1000        -5.3        -7.2    8.94E+01    3.46E+01    2.58E+00
    1500        -4.6        -6.3    2.71E+05    3.28E+05    8.28E-01
    2000        -4.1        -5.4    1.50E+07    2.95E+07    5.06E-01
    2500        -3.7        -4.6    1.66E+08    4.21E+08    3.93E-01
    3000        -3.4        -3.8    8.24E+08    2.41E+09    3.41E-01
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