O + CH3 -> H + H2 + CO

SOURCE:

Slagle, I.R., Sarzynski, D., and Gutman, D. (1987) J. Phys. Chem. 91, 4375.

Seakins, P.W., and Leone, S.R. (1992) J. Phys. Chem. 96, 4478.

COMMENTS:

Served as an optimization variable and new reaction in GRI-Mech 3.0, and was not changed. A 40% branching fraction was used, with 60% yield for reaction 10, O + CH3 = H + CH2O.

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    Temp      delta-S     delta-H      kf          kr         
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        21.1       -69.0    3.73E+13    0.00E+00    
     500        23.1       -67.9    3.73E+13    0.00E+00    
    1000        24.6       -67.2    3.73E+13    0.00E+00    
    1500        24.7       -67.0    3.73E+13    0.00E+00    
    2000        24.6       -67.2    3.73E+13    0.00E+00    
    2500        24.4       -67.7    3.73E+13    0.00E+00    
    3000        24.3       -68.5    3.73E+13    0.00E+00    
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