O + C2H4 -> CH3 + HCO

SOURCE:

Rate expression is a fit to the 2-term expression of Klemm et al. (1990) for the overall rate coefficient multiplied by the 0.65 branching fraction to this channel. Baulch et al. (1992)recommend 0.60.

COMMENTS:

Related reaction is 285 O + C2H4 = H + CH2CHO.

REFERENCES

Klemm et al. (1990)

Klemm, R.B., Sutherland, J.W., Wickramaaratchi, M.A., and Yarwood, G. (1990) J. Phys. Chem. 94, 3354.

Baulch et al. (1992)

Baulch, D.L., Cobos, C.J., Cox, R.A., Esser, C., Frank, P., Just, Th., Kerr, J.A., Pilling, M.J., Troe, J., Walker, R.W., and Warnatz, J. J. (1992) Phys. Chem. Ref. Data 21, 411.

Total rate constant for k(25) + k(285) is the same as the GRI-Mech 1.2 value.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300         9.1       -27.0    2.94E+11    7.09E-11    4.15E+21
     500         9.6       -26.8    8.71E+11    1.38E+00    6.28E+13
    1000         8.9       -27.4    3.45E+12    4.19E+04    8.24E+07
    1500         8.0       -28.4    7.54E+12    9.69E+06    7.77E+05
    2000         7.3       -29.7    1.30E+13    1.90E+08    6.82E+04
    2500         6.7       -31.0    1.98E+13    1.33E+09    1.48E+04
    3000         6.2       -32.4    2.78E+13    5.41E+09    5.12E+03
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