H + HCCO -> CH2(S) + CO

SOURCE:

Miller, J.A., and Bowman, C.T. (1989) Prog. Energy Combust. Sci. 15, 287.

COMMENTS:

No measurements; estimated. Cf. the estimate 1.1E+14 cm3/mol s of Vinckier, C., Schaekers, M., and Peeters, J. (1985) J. Phys. Chem. 89, 508.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300         6.1       -18.2    1.00E+14    2.69E-01    3.72E+14
     500         4.9       -18.7    1.00E+14    6.01E+04    1.66E+09
    1000         2.6       -20.3    1.00E+14    9.93E+08    1.01E+05
    1500         1.4       -21.7    1.00E+14    3.33E+10    3.00E+03
    2000          .7       -23.0    1.00E+14    2.16E+11    4.62E+02
    2500          .2       -24.1    1.00E+14    7.06E+11    1.42E+02
    3000         -.2       -25.2    1.00E+14    1.61E+12    6.20E+01
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